MEDIUM
JEE Main
IMPORTANT
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An organic compound AC6H6O gives dark green colouration with ferric chloride. On treatment with CHCl3 and KOH, followed by acidification gives compound B. Compound B can also be obtained from compound C on reaction with pyridinium chlorochromate (PCC). Identify A, B and C.

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Important Questions on Alcohols, Phenols and Ethers

EASY
JEE Main
IMPORTANT
To synthesise 1 mole of 2-methylpropan-2-ol from Ethylethanoate equivalents of CH3MgBr reagent will be required. (Integer value)
MEDIUM
JEE Main
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An organic compound 'AC9H10O when treated with conc. HI undergoes cleavage to yield compound 'B' and 'C'. 'B' gives yellow precipitate with AgNO3 where as 'C' tautomerizes to 'D'. 'D' gives positive iodoform test. 'A' could be:
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JEE Main
IMPORTANT

Two compounds A and B with same molecular formula C3H6O undergo Grignard reaction with methylmagnesium bromide to give products C and D. Products C and D show following chemical tests.

Test C D
Ceric ammonium nitrate Test Positive Positive
Lucas Test Turbidity obtained after five minutes Turbidity obtained Immediately
Iodoform Test Positive Negative

C and D respectively are

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JEE Main
IMPORTANT

The major aromatic product C in the following reaction sequence will be :

Question Image 

MEDIUM
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IMPORTANT
Which of the following compounds will not be soluble in sodium bicarbonate?
EASY
JEE Main
IMPORTANT
Which one of the following substituents at para-position is most effective in stabilizing the phenoxide Question Image ion ?
MEDIUM
JEE Main
IMPORTANT

The aldehydes which will not form Grignard product with one equivalent of Grignard reagents are
(A) Question Image

(B) Question Image

C Question Image

(D) Question Image